



                               Method Information



                            Method Change History



Operator           Date                Change Information

                   2/25/2003 11:20:57 AMThis method was created at
                                       2/25/2003 11:20:57 AM and based on
                                       method C:\HPCHEM\1\METHODS\DEF_GC.M
                   2/25/2003 11:20:58 AM
                   2/25/2003 11:30:14 AM
                   2/25/2003 11:33:18 AM
                   2/25/2003 11:44:11 AM
                   2/26/2003 2:01:18 PMThis method was created at
                                       2/26/2003 2:01:18 PM and based on
                                       method C:\HPCHEM\1\METHODS\SS_FID.M
                   2/26/2003 2:01:20 PM
Toshikatsu Kura... 2/26/2003 4:26:10 PM
YAN  A.Kumazawa    9/23/2005 3:02:34 PM
MWJ                4/25/2006 4:36:29 PMThis method was created at
                                       4/25/2006 4:36:29 PM and based on
                                       method
                                       C:\HPCHEM\1\METHODS\COOLDOWN.M
MWJ                4/25/2006 4:36:31 PM
MWJ                5/23/2006 4:02:40 PM
MWJ                5/23/2006 4:13:00 PM
MWJ                5/24/2006 5:30:46 PM
MWJ                6/16/2006 8:06:34 PM
MWJ KURI           6/23/2006 11:48:47 AM
MWJ KURI           6/23/2006 8:55:16 PM
MWJ KURI           6/24/2006 7:53:15 PM
MWJ KURI           6/25/2006 1:34:08 PM
MWJ                8/8/2006 8:36:14 PM This method was created at
                                       8/8/2006 8:36:14 PM and based on
                                       method C:\HPCHEM\1\METHODS\JR.M
MWJ                8/8/2006 8:36:15 PM
MWJ                8/10/2006 4:40:17 PM
MWJ KURI           8/21/2006 12:00:36 PM
MWJ KURI           8/23/2006 6:47:34 PM
MWJ KURI           10/3/2006 4:19:07 PM
MWJ_NOIRI          8/1/2007 3:39:43 PM This method was created at
                                       8/1/2007 3:39:43 PM and based on
                                       method
                                       C:\HPCHEM\1\METHODS\CK06-06.M
MWJ_NOIRI          8/1/2007 3:39:44 PM
MWJ_Moriya         8/2/2007 6:25:35 PM
MWJ_Moriya         8/3/2007 3:46:14 PM
MWJ_Moriya         8/4/2007 3:40:34 PM
MWJ_Kurihara       9/23/2007 2:22:14 PM
MWJ_Kurihara       10/10/2007 1:24:22 PM
MWJ_Noiri          10/21/2007 2:27:19 PM
MWJ_kurihara       11/17/2007 6:21:14 PM
MWJ noiri          12/26/2007 5:01:30 PM
MWJ_Kurihara       1/20/2008 12:33:22 AM
NR                 6/25/2008 1:24:36 PMThis method was created at
                                       6/25/2008 1:24:36 PM and based on
                                       method C:\HPCHEM\1\METHODS\HS-VAC.M
NR                 6/25/2008 1:24:42 PMtest





                            Method Change History



Operator           Date                Change Information

NR                 6/25/2008 1:26:02 PM
Kurihara           6/25/2008 5:35:47 PM
Kurihara           10/21/2008 5:25:35 PMThis method was created at
                                       10/21/2008 5:25:35 PM and based on
                                       method C:\HPCHEM\1\METHODS\080625.M
Kurihara           10/21/2008 5:25:36 PM
Kawai              1/29/2009 1:25:43 PM
Kawai              1/29/2009 1:26:38 PM
Kawai              2/11/2009 11:02:23 AMThis method was created at
                                       2/11/2009 11:02:23 AM and based on
                                       method C:\HPCHEM\1\METHODS\HS-VAC.M
Kawai              2/11/2009 11:02:24 AM
Kawai              2/11/2009 11:03:59 AM
Kawai              2/11/2009 12:42:24 PM
Kawai              2/11/2009 2:54:54 PM
Kawai              2/12/2009 10:35:11 AM
Kawai              2/12/2009 3:39:28 PM
Kawai              2/12/2009 3:39:53 PM
Kawai              2/12/2009 3:40:27 PMThis method was created at
                                       2/12/2009 3:40:27 PM and based on
                                       method
                                       C:\HPCHEM\1\METHODS\090211A.M
Kawai              2/12/2009 3:40:27 PM
Noiri              2/12/2009 3:42:41 PMThis method was created at
                                       2/12/2009 3:42:41 PM and based on
                                       method
                                       C:\HPCHEM\1\METHODS\TEST_HSS.M
Noiri              2/12/2009 3:42:41 PM
MWJ_Kurihara       4/3/2009 3:37:13 PM This method was created at
                                       4/3/2009 3:37:13 PM and based on
                                       method
                                       C:\HPCHEM\1\METHODS\090211A.M
MWJ_Kurihara       4/3/2009 3:37:14 PM
MWJ_Kurihara       4/3/2009 3:44:40 PM
MWJ_Kurihara       4/3/2009 5:57:44 PM
MWJ_Kurihara       4/3/2009 9:00:13 PM
MWJ_Kurihara       4/4/2009 9:12:29 AM
MWJ_Kurihara       4/6/2009 4:21:18 PM
MWJ_moriya and ... 8/27/2009 9:39:07 AMupdated calibration curves
MWJ_moriya and ... 8/27/2009 10:11:51 AMupdate report layout
MWJ_moriya         9/6/2009 5:16:08 AM
MWJ_moriya         9/6/2009 8:26:04 AM
MWJ_hatakeyama     9/6/2009 10:20:30 AM
MWJ_hatakeyama     9/6/2009 2:39:19 PM
Verena Heuer       9/8/2009 4:39:51 AM
kawai/mwj          9/9/2009 12:47:11 AMRecalcurate calibration curve
moriya/mwj         9/9/2009 7:04:35 AM
Kurihara/MWJ       10/20/2009 9:49:13 AM091020
Kurihara/MWJ       11/7/2009 3:11:48 PMdummy calibration curve(miyabe)
Miyabes/MWJ        11/7/2009 7:23:23 PMCalibration for Exp904



                               Run Time Checklist

            Pre-Run Cmd/Macro:  off




             Data Acquisition:  on

       Standard Data Analysis:  on

     Customized Data Analysis:  off

                Save GLP Data:  off

           Post-Run Cmd/Macro:  off


        Save Method with Data:  off



                         Injection Source and Location

     Injection Source:   Manual

     Injection Location: Front
=============================================================================
                                6890 GC METHOD
=============================================================================

OVEN
   Initial temp:  100 'C (On)              Maximum temp:  325 'C
   Initial time:  5.50 min                 Equilibration time:  3.00 min
   Ramps:
      #  Rate  Final temp  Final time
      1 50.00      140        4.00
      2   0.0(Off)
   Post temp:  50 'C
   Post time:  0.00 min
   Run time:  10.30 min

FRONT INLET (SPLIT/SPLITLESS)           BACK INLET (PURGED PACKED)
   Mode:  Split                            Initial temp:  110 'C (On)
   Initial temp:  50 'C (Off)              Flow:  33.8 mL/min (On)
   Pressure:  0.00 psi (Off)               Gas type:  Helium
   Total flow:  45.0 mL/min
   Gas saver:  Off
   Gas type:  Helium

COLUMN 1                                COLUMN 2
   Packed Column                           Packed Column
   Model Number:  GL HayeSep R             Mode:  ramped pressure
   O.D.1/8" * 8FT                          Initial pressure:  1.00 psi
   Max temperature:  250 'C                Initial time:  0.00 min
   Mode:  constant flow                       #  Rate  Final pres  Final time
   Nominal initial flow:  32.8 mL/min         1   0.0(Off)
   Inlet:  Back Inlet                      Post pressure:  0.00 psi
   Outlet:  Front Detector                 Inlet:  Aux 3 Pressure Controller
   Outlet pressure:  ambient               Outlet:  (unspecified)
                                           Outlet pressure:  ambient

FRONT DETECTOR (FID)                    BACK DETECTOR (NO DET)
   Temperature:  250 'C (On)
   Hydrogen flow:  40.0 mL/min (On)
   Air flow:  450.0 mL/min (On)
   Mode:  Constant makeup flow
   Makeup flow:  25.0 mL/min (On)
   Makeup Gas Type: Helium
   Flame:  On
   Electrometer:  On



   Lit offset:  2.0

SIGNAL 1                                SIGNAL 2
   Data rate:  20 Hz                       Data rate:  20 Hz
   Type:  front detector                   Type:  front detector
   Save Data:  On                          Save Data:  Off
   Zero:  0.0 (Off)                        Zero:  0.0 (Off)
   Range:  0                               Range:  0
   Fast Peaks:  Off                        Fast Peaks:  Off
   Attenuation:  0                         Attenuation:  0

COLUMN COMP 1                           COLUMN COMP 2
   Derive from front detector              Derive from front detector

THERMAL AUX 1                           AUX PRESSURE 3
   Use:  Valve Box Heater                  Description:  VALVE
   Description:  VALVE BOX(MAX 225C)       Gas Type:  Helium
   Initial temp:  110 'C (On)              Driving Column 2
   Initial time:  0.00 min                 Initial pressure:  1.00 psi (On)
      #  Rate  Final temp  Final time
      1   0.0(Off)

AUX PRESSURE 4                          AUX PRESSURE 5
   Description:  NOT USE                   Description:  HSS VIALPRESS
   Gas Type:  Helium                       Gas Type:  Helium
   Initial pressure:  0.00 psi (Off)       Initial pressure:  10.00 psi (On)
                                           Initial time:  0.00 min
                                              #  Rate  Final pres  Final time
                                              1   0.0(Off)

VALVES                                  POST RUN
   Valve 1  Switching On                   Post Time: 0.00 min
      Description:  VALVE 1
   Valve 2  Switching Off
      Description:
   Valve 3  Switching Off
      Description:

TIME TABLE
   Time       Specifier                     Parameter & Setpoint


                                GC Injector


     Front Injector:
          Injector not configured, use these parameters if it becomes configured
        Sample Washes                 0
        Sample Pumps                  6
        Injection Volume            1.0 microliters
        Syringe Size               10.0 microliters
        PostInj Solvent A Washes      0
        PostInj Solvent B Washes      0
        Viscosity Delay               0 seconds
        Plunger Speed              Fast

     Back Injector:
          Injector not configured, use these parameters if it becomes configured
        Sample Washes                 0
        Sample Pumps                  6
        Injection Volume            1.0 microliters
        Syringe Size               10.0 microliters
        PostInj Solvent A Washes      0
        PostInj Solvent B Washes      0
        Viscosity Delay               0 seconds



        Plunger Speed              Fast
========================================================================
                           Integration Events                           
========================================================================

Results will be produced with the enhanced integrator.

------------------------------------------------------------------------
                Default Integration Event Table "Event"                 
------------------------------------------------------------------------

                Event                                  Value     Time
|------------------------------------------------|-------------|-------|
 Initial Slope Sensitivity                              1.000   Initial
 Initial Peak Width                                     0.040   Initial
 Initial Area Reject                                    1.000   Initial
 Initial Height Reject                                  1.700   Initial
 Initial Shoulders                                      OFF     Initial

------------------------------------------------------------------------
          Detector Default Integration Event Table "Event_TCD"          
------------------------------------------------------------------------

                Event                                  Value     Time
|------------------------------------------------|-------------|-------|
 Initial Slope Sensitivity                            100.000   Initial
 Initial Peak Width                                     0.040   Initial
 Initial Area Reject                                    1.000   Initial
 Initial Height Reject                                  1.000   Initial
 Initial Shoulders                                      OFF     Initial

------------------------------------------------------------------------
          Detector Default Integration Event Table "Event_ADC"          
------------------------------------------------------------------------

                Event                                  Value     Time
|------------------------------------------------|-------------|-------|
 Initial Slope Sensitivity                             20.000   Initial
 Initial Peak Width                                     0.040   Initial
 Initial Area Reject                                    1.000   Initial
 Initial Height Reject                                  1.000   Initial
 Initial Shoulders                                      OFF     Initial

------------------------------------------------------------------------
          Detector Default Integration Event Table "Event_ECD"          
------------------------------------------------------------------------

                Event                                  Value     Time
|------------------------------------------------|-------------|-------|
 Initial Slope Sensitivity                            100.000   Initial
 Initial Peak Width                                     0.080   Initial
 Initial Area Reject                                    1.000   Initial
 Initial Height Reject                                  1.000   Initial
 Initial Shoulders                                      OFF     Initial

------------------------------------------------------------------------
          Detector Default Integration Event Table "Event_NPD"          
------------------------------------------------------------------------

                Event                                  Value     Time
|------------------------------------------------|-------------|-------|
 Initial Slope Sensitivity                            500.000   Initial
 Initial Peak Width                                     0.040   Initial
 Initial Area Reject                                    1.000   Initial
 Initial Height Reject                                  1.000   Initial
 Initial Shoulders                                      OFF     Initial

------------------------------------------------------------------------
          Detector Default Integration Event Table "Event_FPD"          
------------------------------------------------------------------------

                Event                                  Value     Time
|------------------------------------------------|-------------|-------|
 Initial Slope Sensitivity                             50.000   Initial
 Initial Peak Width                                     0.040   Initial
 Initial Area Reject                                    1.000   Initial
 Initial Height Reject                                  1.000   Initial
 Initial Shoulders                                      OFF     Initial

------------------------------------------------------------------------
         Detector Default Integration Event Table "Event_uECD"          
------------------------------------------------------------------------

                Event                                  Value     Time
|------------------------------------------------|-------------|-------|
 Initial Slope Sensitivity                            500.000   Initial
 Initial Peak Width                                     0.080   Initial
 Initial Area Reject                                    1.000   Initial
 Initial Height Reject                                  1.000   Initial
 Initial Shoulders                                      OFF     Initial

------------------------------------------------------------------------
          Detector Default Integration Event Table "Event_FID"          
------------------------------------------------------------------------

                Event                                  Value     Time
|------------------------------------------------|-------------|-------|
 Initial Slope Sensitivity                             50.000   Initial
 Initial Peak Width                                     0.040   Initial
 Initial Area Reject                                   20.000   Initial
 Initial Height Reject                                  1.000   Initial
 Initial Shoulders                                      OFF     Initial

Apply Manual Integration Events: No

Advanced Baseline              : No

=====================================================================
                          Calibration Table                          
=====================================================================

 

Calib. Data Modified  :      Saturday, November 07, 2009 7:22:44 PM

Calculate             :      External Standard
Based on              :      Peak Area

Rel. Reference Window :      5.000 %
Abs. Reference Window :      0.000 min
Rel. Non-ref. Window  :      5.000 %
Abs. Non-ref. Window  :      0.000 min
Do not use Multiplier & Dilution Factor with ISTDs
Uncalibrated Peaks    :      not reported
Partial Calibration   :      Yes, identified peaks are recalibrated
Correct All Ret. Times:      No, only for identified peaks

Curve Type            :      Linear
Origin                :      Included
Weight                :      Equal

Recalibration Settings:       
Average Response      :      Average all calibrations
Average Retention Time:      Floating Average New 75%

Calibration Report Options :
    Printout of recalibrations within a sequence:
        Calibration Table after Recalibration
        Normal Report after Recalibration
    If the sequence is done with bracketing:
        Results of first cycle (ending previous bracket)

Signal 1: FID1 A, 

RetTime   Lvl   Amount      Area     Amt/Area  Ref Grp Name          
 [min] Sig      [ppm]                                                
-------|--|--|----------|----------|----------|---|--|---------------
  1.474  1  1 1.07000e4  8.33163e4  1.28426e-1        Methane                                           
  2.125  1  1 1.00000e4  1.36430e5  7.32976e-2        Ethylene                                          
  2.372  1  1 9980.00000 1.41756e5  7.04027e-2        Ethane                                            
  5.050  1  1 1.06000e4  2.07754e5  5.10219e-2        Propylene                                         
  5.439  1  1 9840.00000 2.10536e5  4.67380e-2        Propane                                           
  8.646  1  1 9670.00000 2.77027e5  3.49064e-2        iso-Butane                                        
  9.618  1  1 9530.00000 2.63376e5  3.61840e-2        n-Butane                                          
=====================================================================
                           Peak Sum Table                            
=====================================================================

***No Entries in table***
=====================================================================
